New ultrarapid-scanning interferometer for FT-IR spectroscopy with microsecond time-resolution

A novel Fourier-transform infrared (FT-IR) rapid-scan spectrometer has been developed (patent pending EP14194520.4) which yields 1000 times higher time resolution as compared to conventional rapid-scanning spectrometers. The central element to achieve faster scanning rates is based on a sonotrode whose front face represents the movable mirror of the interferometer. A prototype spectrometer with a time resolution of 13 μs was realized, capable of fully automated long-term measurements with a flow cell for liquid samples, here a photosynthetic membrane protein in solution. The performance of this novel spectrometer is demonstrated by recording the photoreaction of bacteriorhodopsin initiated by a short laser pulse that is synchronized to the data recording. The resulting data are critically compared to those obtained by step-scan spectroscopy and demonstrate the relevance of performing experiments on proteins in solution. The spectrometer allows for future investigations of fast, non-repetitive processes, whose investigation is challenging to step-scan FT-IR spectroscopy

Calculation of coercivity of magnetic nanostructures at finite temperatures

We report a finite temperature micromagnetic method (FTM) that allows for the calculation of the coercive field of arbitrary shaped magnetic nanostructures at time scales of nanoseconds to years. Instead of directly solving the Landau-Lifshitz-Gilbert equation, the coercive field is obtained without any free parameter by solving a non linear equation, which arises from the transition state theory. The method is applicable to magnetic structures where coercivity is determined by one thermally activated reversal or nucleation process. The method shows excellent agreement with experimentally obtained coercive fields of magnetic nanostructures and provides a deeper understanding of the mechanism of coercivity.Comment: submitted to Phys. Rev.

Gastrocnemius medialis contractile behavior during running differs between simulated Lunar and Martian gravities

The international partnership of space agencies has agreed to proceed forward to the Moon sustainably. Activities on the Lunar surface (0.16 g) will allow crewmembers to advance the exploration skills needed when expanding human presence to Mars (0.38 g). Whilst data from actual hypogravity activities are limited to the Apollo missions, simulation studies have indicated that ground reaction forces, mechanical work, muscle activation, and joint angles decrease with declining gravity level. However, these alterations in locomotion biomechanics do not necessarily scale to the gravity level, the reduction in gastrocnemius medialis activation even appears to level off around 0.2 g, while muscle activation pattern remains similar. Thus, it is difficult to predict whether gastrocnemius medialis contractile behavior during running on Moon will basically be the same as on Mars. Therefore, this study investigated lower limb joint kinematics and gastrocnemius medialis behavior during running at 1 g, simulated Martian gravity, and simulated Lunar gravity on the vertical treadmill facility. The results indicate that hypogravity-induced alterations in joint kinematics and contractile behavior still persist between simulated running on the Moon and Mars. This contrasts with the concept of a ceiling effect and should be carefully considered when evaluating exercise prescriptions and the transferability of locomotion practiced in Lunar gravity to Martian gravity

Contractile behavior of the gastrocnemius medialis muscle during running in simulated hypogravity

Vigorous exercise countermeasures in microgravity can largely attenuate muscular degeneration, albeit the extent of applied loading is key for the extent of muscle wasting. Running on the International Space Station is usually performed with maximum loads of 70% body weight (0.7 g). However, it has not been investigated how the reduced musculoskeletal loading affects muscle and series elastic element dynamics, and thereby force and power generation. Therefore, this study examined the effects of running on the vertical treadmill facility, a ground-based analog, at simulated 0.7 g on gastrocnemius medialis contractile behavior. The results reveal that fascicle−series elastic element behavior differs between simulated hypogravity and 1 g running. Whilst shorter peak series elastic element lengths at simulated 0.7 g appear to be the result of lower muscular and gravitational forces acting on it, increased fascicle lengths and decreased velocities could not be anticipated, but may inform the development of optimized running training in hypogravity. However, whether the alterations in contractile behavior precipitate musculoskeletal degeneration warrants further study

Probing the Edge of the Solar System: Formation of an Unstable Jet-Sheet

The Voyager spacecraft is now approaching the edge of the solar system. Near the boundary between the solar system and the interstellar medium we find that an unstable ``jet-sheet'' forms. The jet-sheet oscillates up and down due to a velocity shear instability. This result is due to a novel application of a state-of-art 3D Magnetohydrodynamic (MHD) code with a highly refined grid. We assume as a first approximation that the solar magnetic and rotation axes are aligned. The effect of a tilt of the magnetic axis with respect to the rotation axis remains to be seen. We include in the model self-consistently magnetic field effects in the interaction between the solar and interstellar winds. Previous studies of this interaction had poorer spatial resolution and did not include the solar magnetic field. This instability can affect the entry of energetic particles into the solar system and the intermixing of solar and interstellar material. The same effect found here is predicted for the interaction of rotating magnetized stars possessing supersonic winds and moving with respect to the interstellar medium, such as O stars.Comment: 9 pages, 4 figures, accepted for publication in ApJ

Fluid flow and mass flux determinations at vent sites on the Cascadia margin accretionary prism

Fluid venting from the toe of the accretionary prism off Oregon was measured in situ during a series of dives with DSRV Alvin in 1987 and 1988. A benthic chamber was placed over active vent sites to sequentially collect samples of venting fluids and to make direct measurements of discharge rates. Calibrated flow meter measurements and flow rates determined from dissolved methane transfer indicate that discharge from two vent sites, Alvin 1428 and Alvin 1900, ranges roughly between 100 and 500 L m−2 d−1. with the most reliable estimates falling in the range of 125–150 L m−2d−1. These rates imply subsurface advective flow on the order of 100 m yr−1. Comparison of observed discharge rates with rates calculated for steady state expulsion supported by accretion-related compaction indicates that the observed flow is greater than predicted flow by several orders of magnitude. The disparity dictates that fluids are not derived locally, but are transported laterally within the prism, or that flow is not steady state and that individual vents are short-lived features in the ongoing accretion process

Evaluating Molecular Cobalt Complexes for the Conversion of N_2 to NH_3

We report a molecular Co−N_2 complex that generates a greater-than-stoichiometric yield of NH_3 (>200% NH_3 per Co−N_2 precursor) via the direct reduction of N_2 with protons and electrons. A comparison of the featured Co−N_2 complex with structurally related Co−N_2 and Fe−N_2 species shows how remarkably sensitive the N_2 reduction performance of potential precatalysts is. As discussed, structural and electronic effects are relevant to Co/Fe−N_2 conversion activity, including π basicity, charge state, and geometric flexibility

Latitudinal Dependence of the Radial IMF Component - Interplanetary Imprint

Ulysses measurements have confirmed that there is no significant gradient with respect to heliomagnetic latitude in the radial component, B(sub r,), of the interplanetary magnetic field. There are two processes responsible for this observation. In the corona, the plasma beta is much less than 1, except directly above streamers, so both longitudinal and latitudinal (meridional) gradients in field strength will relax, due to the transverse magnetic pressure gradient force, as the solar wind carries magnetic flux away from the Sun. This happens so quickly that the field is essentially uniform by 5 solar radius. Beyond 10 solar radius, beta is greater than 1 and it is possible for a meridional thermal pressure gradient to redistribute magnetic flux - an effect apparently absent in Ulysses and earlier ICE and Interplanetary Magnetic Physics (IMP) data. We discuss this second effect here, showing that its absence is mainly due to the perpendicular part of the anisotropic thermal pressure gradient in the interplanetary medium being too small to drive significant meridional transport between the Sun and approx. 4 AU. This is done using a linear analytic estimate of meridional transport. The first effect was discussed in an earlier paper